Mauricio Gomes
Constantino
Publicações
A) Monografia, Dissertação, Teses
1. Monografia de conclusão de graduação
(13,3 MB): "Cinética
da Mutarrotação da Glicose", FFCLRP, 1970.
2. Dissertação de Mestrado (12,9 MB): "Sobre
a Síntese de Bakkenolida", IQUSP, 1974.
3. Tese de Doutoramento (55,7 MB): "Caminhos
Sintéticos para Bakkenolidas", IQUSP, 1977.
4. Tese de Livre-docência (16,96 MB): "Sobre
a Síntese de Ácido Abscísico", FFCLRP-USP, 1982.
B) Trabalhos publicados em periódicos
- S. F. Campbell, M. G. Constantino, T. J. Brocksom and N. Petragnani, "An Approach
to the Synthesis of Bakkenolide A", Synth. Commun. 1975, 5,
353-358.
DOI:
10.1080/00397917508062089
- N. Petragnani, T. J. Brocksom, H. M. C. Ferraz and M. G. Constantino, "The
Synthesis of a b -methylene-g
-spirolactone", Synthesis, 1977, 112-113.
http://www.thieme-connect.com/ejournals/toc/synthesis/1448
- T. J. Brocksom, M. G. Constantino and H. M. C. Ferraz, "Synthesis of Spiro-b -methylene-g -butyrolactones", Synth.
Commun. 1977, 7, 483-493.
DOI:
10.1080/00397917708050784
- N. Petragnani, T. J. Brocksom, H. M. C. Ferraz e M. G. Constantino, "Síntese de
uma b -Metileno-g
-Espirolactona", Química Nova 1978, 1(2), 8-10.
http://quimicanova.sbq.org.br/qn/qnol/1978/vol1n2/v01_n2_%20(4).pdf
- J. A. Marshall, M. G. Constantino and T. H. Black, "A Short Synthesis of
Symmetrical Betweenanenes", Synth. Commun. 1980, 10, 689-692.
DOI:
10.1080/00397918008065651
- M. G. Constantino, P. M. Donate and N. Petragnani, "Synthesis of (± )-1-(2,6,6-Trimethyl-4-hydroxycyclohexenyl)-1,3-butanedione (1), a
Marine Natural Product", Tetrahedron Lett. 1982, 23,
1051-1054.
DOI:
10.1016/S0040-4039(00)87019-7
- T. J. Brocksom and M. G. Constantino, "Diels-Alder Reactions of Piperylenes", J.
Org. Chem. 1982, 47, 3450-3453.
DOI:
10.1021/jo00139a013
- T. J. Brocksom e M. G. Constantino, "The Diels-Alder Reaction of Cis- and
Trans-Piperylenes with Various Maleic and Citraconic Anhydride Derivatives", An.
Acad. Brasil. Ciênc. 1982, 54, 655-661.
- M. G. Constantino, P. M. Donate and N. Petragnani, "An Efficient Synthesis of (± )-Abscisic Acid", J. Org. Chem. 1986, 51,
253-254.
DOI:
10.1021/jo00352a027
- M. G. Constantino, P. M. Donate and N. Petragnani, "Hydration of Diacetylene
Compounds. Synthesis of a Marine Natural Product: (±
)-1-(2,6,6-Trimethyl-4-hydroxycyclohexenyl)-1,3-butanedione", J. Org. Chem. 1986,
51, 387-390.
DOI:
10.1021/jo00353a022
- M. G. Constantino, "Um Acionador Automático de Seringas", Química Nova
1987, 10, 21-23.
http://quimicanova.sbq.org.br/qn/qnol/1987/vol10n1/v10_n1_%20(4).pdf
- H. J. Bestmann, A. B. Attygalle, J. Glasbrenner, R. Riemer, O. Vostrovsky, M. G.
Constantino, G. Melikian and E. D. Morgan, "Identification of the Volatile Components
of the Mandibular Gland Secretion of the Ant Manica rubida: Structure Elucidation,
Synthesis and Absolute Configuration of Manicone", Liebigs Ann. Chem. 1988,
55-60.
DOI:
10.1002/jlac.198819880111
- M. G. Constantino e E. F. Medeiros, "Um Gerador de Ozônio de Fácil
Construção", Química Nova 1988, 11, 259-261.
http://quimicanova.sbq.org.br/qn/qnol/1988/vol11n2/v11_n2_%20(18).pdf
- M. G. Constantino, "Utilização de Micro-Computadores em Aulas de Ressonância
Magnética Nuclear de Próton", Química Nova 1988, 11,
299-303.
http://quimicanova.sbq.org.br/qn/qnol/1988/vol11n3/v11_n3_%20(6).pdf
- M. G. Constantino, P. Losco and E. E. Castellano, "A Novel Synthesis of (± )-Abscisic Acid", J. Org. Chem. 1989, 54,
681-683.
DOI:
10.1021/jo00264a032
- E. E. Castellano, J. Zukermann-Schpector, M. G. Constantino and P. Losco,
"Structural Studies on Abscisic Acid Synthesis Intermediates:
(1)-5,6-Dihydro...", Acta Cryst. 1989, C45, 970-972.
DOI:
10.1107/S0108270188014167
- M. G. Constantino e G. V. J. Silva, "Um Desumidificador de Ar para Aparelhos de
RMN", Química Nova 1989, 12, 174-176.
http://quimicanova.sbq.org.br/qn/qnol/1989/vol12n2/v12_n2_%20(9).pdf
- I. Carvalho, M. G. Constantino e G. V. J. Silva, "Simples e Eficiente Método para
Dosar LDA", Química Nova 1989, 12, 177-178.
http://quimicanova.sbq.org.br/qn/qnol/1989/vol12n2/v12_n2_%20(10).pdf
- M. G. Constantino e M. C. Prado, "Uma Síntese Formal de Capsorubina", Química
Nova 1991, 14, 22.
http://quimicanova.sbq.org.br/qn/qnol/1991/vol14n1/v14_n1_%20(4).pdf
- M. G. Constantino e E. R. Oliveira, "Um Seguro Controle de Aquecimento para
Laboratório", Química Nova 1991, 14, 120-121.
http://quimicanova.sbq.org.br/qn/qnol/1991/vol14n2/v14_n2_%20(11).pdf
- M. G. Constantino, M. Beltrame Jr., E. F. Medeiros and G. V. J. Silva, "Synthesis
of an Allylic Spiro-Lactone", Synth. Commun. 1992, 22,
2859-2864.
DOI:
10.1080/00397919208021553
- P. Losco, H. M. C. Ferraz e M. G. Constantino, "Uma Síntese Formal do Ácido
Abscísico", Química Nova 1992, 15, 18-20.
http://quimicanova.sbq.org.br/qn/qnol/1992/vol15n1/v15_n1_%20(4).pdf
- M. G. Constantino and M. Beltrame Jr., "Synthesis of Abscisic Acid", Trends
in Organic Chemistry 1993, 4, 371-378.
- G. V. J. da Silva, M. M. M. Pelisson and M. G. Constantino, "Synthesis of
3-Substituted Furans", Tetrahedron Lett. 1994, 35, 7327-7330.
DOI:
10.1016/0040-4039(94)85305-3
- J. Zukerman-Schpector, M. G. Constantino and M. Beltrame Jr., J. Chem. Cryst. 1995,
25, 413-416.
DOI:
10.1007/BF01665279
- M. G. Constantino, M. Beltrame Jr., G. V. J. da Silva and J. Zukerman-Schpector, "A
Novel Asymmetric Synthesis of (+)-Artemisinin", Synth. Commun. 1996, 26,
321-329.
DOI:
10.1080/00397919608003621
- M. G. Constantino, I. Carvalho, G. V. J. da Silva and F. C. Archanjo, "Hydration of
Acetylenic Esters: Synthesis of b -Keto-Esters", Molecules
1996, 1, 72-78.
http://www.springerlink.com/content/e2ahdlhn4k2x/?p=3358204f423c48b9b910be67c45ad9b6&pi=19
http://www.springerlink.com/content/8w5bc9c1q0nrrrj4/fulltext.pdf
- M. G. Constantino, L. G. O. Matias, G. V. J. da Silva, V. C. G. Heleno and M. T. P.
Gambardella, "Stereoselective Synthesis of b -Hydroxy- and
b -Ethoxy-d -lactones: Model
Structures for Compounds Isolated from Otoba parvifolia", Synth. Commun.
1997, 27, 4285-4295.
DOI:
10.1080/00397919708005052
- M. G. Constantino, G. V. J. da Silva e M. M. M. Pelisson, "Moléculas em Três
Dimensões: Um Estereoscópio Para Computador", Química Nova 1998, 21,
337-340.
http://quimicanova.sbq.org.br/qn/qnol/1998/vol21n3/v21_n3_15.pdf
- M. G. Constantino e A. X. de Souza, "Modelos Para o Carbono sp3: Quatro
Pirâmides no Tetraedro", Química Nova 1998, 21,
662-665.
http://quimicanova.sbq.org.br/qn/qnol/1998/vol21n5/v21_n5_%20(21).pdf
- M. G. Constantino and G. V. J. da Silva, "Stereochemistry in Substituted
Cyclopentanes: An Approach to the Analysis by Proton NMR", Tetrahedron 1998,
54, 11363-11374.
DOI:
10.1016/S0040-4020(98)00630-9
- M. G. Constantino, L. G. O. Matias, G. V. J. da Silva, E. Barbieri e M. T. P.
Gambardella, "Stereoselective Sodium Borohydride Reductions of Cyclopentanones:
Influence of Ceric Chloride on the Stereochemistry of Reaction", Química Nova,
1998, 21, 719-721.
http://quimicanova.sbq.org.br/qn/qnol/1998/vol21n6/v21_n6_%20(8).pdf
- P. M. Donate, M. G. Constantino, R. da Silva and S. Pedersoli, "Synthesis of
Substituted g-Butyrolactones:
b-Hydroxymethyl-, b-Methylene and
Cyclopropane Derivatives", Synth. Commun. 1999, 29,
2923-2936.
DOI:
10.1080/00397919908086464
- M. G. Constantino, P. M. Donate, D. Frederico, T. V. Carvalho, L. E. Cardoso and J.
Zukerman-Schpector, "Ring Contraction Through Epoxide Rearrangement: a Formal
Synthesis of Capsorubin", Synth. Commun. 2000, 30,
3327-3340.
DOI:
10.1080/00397910008086973
- M. G. Constantino e G. V. J. da Silva, "A Transformada de Fourier em Basic", Química
Nova 2000, 23, 413-417.
http://quimicanova.sbq.org.br/qn/qnol/2000/vol23n3/v23_n3_(20).pdf
- G. V. J. da Silva, V. C. G. Heleno and M. G. Constantino, "Reduction and
Preparation of a Phthalimide Derivative from a Furo-heliangolide", Molecules
2000, 5, 908-915.
http://www.mdpi.org/molecules/papers/50600908.pdf
Reprint.
- M. G. Constantino, A. Beatriz and G. V. J. da Silva, "A Model Synthesis of the
Bicyclic Core Structure of the Furanoheliangolide Sesquiterpenes", Tetrahedron
Lett. 2000, 41, 7001-7004 .
DOI:
10.1016/S0040-4039(00)01198-9
- L. G. O. Matias e M. G. Constantino, "Síntese de Ciclopentanos
Funcionalizados", Anais Assoc. Bras. Quím. 2000, 49,
89-92.
http://allchemy.iq.usp.br/estruturando/revistas/anais-492.html
- M. G. Constantino, A. Beatriz, G. V. J. da Silva and J. Zukerman-Schpector,
"Synthetic Studies on the Diels-Alder Adduct from 3,4-Dimethoxyfuran and
Benzoquinone", Synth. Commun. 2001, 31, 3329-3336.
DOI:
10.1081/SCC-100106044
- M. G. Constantino, V. Lacerda Jr., G. V. J. da Silva, L. Tasic and R. Rittner,
"Principal Component Analysis of Long Range "W" Coupling Constants of Some
Cyclic Compounds", J. Mol. Struc. 2001, 597/1-3,
129-136.
DOI:
10.1016/S0022-2860(01)00591-9
- J. Zukerman-Schpector, I. Caracelli, M. Vega, M. G. Constantino, A. Beatriz e G. V. J.
da Silva, "Two Polycyclic Compounds Derived from a Diels-Alder Reaction", Acta
Cryst. 2001, C57, 646-648.
DOI:
10.1107/S0108270101003365
- M. G. Constantino, V. Lacerda Jr. e V. Aragão, "Niobium Pentachloride Catalysed
Ring Opening of Epoxides", Molecules 2001, 6,
770-776.
http://www.mdpi.org/molecules/papers/60900770.pdf
Reprint.
- M. G. Constantino, V. Lacerda Jr. e G. V. J. da Silva, "Niobium Pentachloride
Activation of Enone Derivatives: Diels-Alder and Conjugate Addition Products", Molecules
2002, 7, 456-465.
http://www.mdpi.org/molecules/papers/70500456.pdf
Reprint.
- M. G. Constantino, A. X. de Souza e G. V. J. da Silva, "Synthetic Studies on
Diels-Alder Adducts: Intramolecular Interactions Between Two Functions", Molecules
2002, 7, 475-486.
http://www.mdpi.org/molecules/papers/70600475.pdf
Reprint.
- M. G. Constantino e G. V. J. da Silva, "Chemical Equilibrium, Free Energy and
Entropy of Mixing", Chem. Educator 2002, 7,
349-353.
DOI:
10.1007/s00897020613a
http://www.springerlink.com/content/k3v8r5888305864j/fulltext.pdf.
- M. G. Constantino, K. T. de Oliveira, A. Beatriz e G.
V. J. da Silva, "A Synthetic Approach to Bicyclo[6.2.1]undecane Ring Systems",
Tetrahedron Lett. 2003, 44, 2641-2643.
DOI:
10.1016/S0040-4039(03)00377-0
- M. G. Constantino, V. Lacerda Jr. e G. V. J. da Silva,
"An Efficient Synthesis of 3-Hydroxychromone Using Niobium Pentachloride",
J. Heterocyclic Chem. 2003, 40, 369-371.
- M. G. Constantino, V. Lacerda Jr. and G. V. J. da
Silva, "Detailed Assignments of 1H and 13C NMR Spectral
Data of 14 Cyclopentane Derivatives", Magn. Reson. Chem. 2003,
41, 641-643.
DOI:
10.1002/mrc.1221
- M. G. Constantino, K. T. de Oliveira, A. Beatriz e G.
V. J. da Silva, "Analysis of the 1H and 13C NMR Spectra
of Bicyclo[6.2.1]undecane Ring Systems", Magn. Reson. Chem. 2003,
41, 726-728.
DOI:
10.1002/mrc.1233
- P. M. Donate, D. Frederico, R. da Silva, M. G.
Constantino, G. Del Ponte e P. S. Bonato, "Asymmetric Synthesis of
g-Butyrolactones by
Enantioselective Hydrogenation of Butenolides", Tetrahedron:Asymmetry
2003, 14, 3253-3256.
DOI:
10.1016/j.tetasy.2003.08.031
- D. Frederico, P. M. Donate,
M. G. Constantino, E. S. Bronze e M. I. Sairre, "A Short and Efficient
Synthesis of Crocetin-dimethylester and Crocetindial", J. Org. Chem
2003, 68, 9126-9128.
DOI:
10.1021/jo034545y
- V. C. G. Heleno, A. E. M.
Crotti, M. G. Constantino, N. P. Lopes e J. L. C. Lopes, "Total Assignment of
1H and 13C NMR Data for the Sesquiterpene Lactone
15-Deoxygoyazensolide", Magn. Reson. Chem. 2004, 42,
364-367.
DOI:
10.1002/mrc.1314
- M. G. Constantino, L. C. da Silva
Filho,
A.
Cunha
Neto,
V. C. G.
Heleno,
G. V. J. da Silva e J. L. C. Lopes, “Structural Assignment of Diels-Alder
Adducts: an Experimental and Theoretical
Approach”,
Spectrochimica Acta Part A 2005, 61(1-2), 171-176.
DOI:
10.1016/j.saa.2004.04.002
- M. G. Constantino, V.
L.
Júnior,
L. C. da Silva
Filho
e G. V. J. da Silva, “Niobium (V) Chloride Mediated Preparation of b
Chloro-a,b-Unsaturated Ketones”, Letters in Organic Chemistry, 2004,
1(4), 360-364.
http://www.bentham.org/loc/contabs/loc1-4.htm
- M. G. Constantino, V.
L.
Júnior
e G. V. J. da Silva, “Detailed Assignments of 1H and
13C
NMR Spectral
Data
0f 13 b-Substituted
Cycloenones”, Magn. Reson. Chem. 2005, 43(4), 346-347.
DOI:
10.1002/mrc.1547
- V. Aragão, M. G. Constantino,
A. Beatriz and G. V. J. da Silva, “Synthesis of
1-Methyl-3-oxo-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic Acid Methyl Ester”,
Molecules 2005, 10(11), 1413-1418.
http://www.mdpi.org/molecules/papers/10111413.pdf
- L. C. da Silva
Filho,
V. L.
Júnior,
M. G. Constantino, G. V. J. da Silva e P. R. Invernize, “High
Stereoselectivity on Low Temperature Diels-Alder Reactions”, Beilstein
Journal of Organic Chemistry 2005, 1, 14.
DOI:
10.1186/1860-5397-1-14
- K. T.
Oliveira,
V. L.
Júnior,
M. G. Constantino, P. M. Donate, G. V. J. da Silva, T. J. Brocksom e D.
Frederico, “Analysis of a Cycloheptenone Derivative: an Experimental and
Theoretical
Approach”,
Spectrochimica Acta Part A 2006, 63(3), 709-713.
DOI:
10.1016/j.saa.2005.06.023
- V. L.
Júnior,
G. V. J. da Silva, M. G. Constantino, C. F. Tormena, R. Thomas Williamson e B.
L. Márquez, “Long-range JCH Heteronuclear Coupling Constants
in Cyclopentane Derivatives”, Magn. Reson. Chem. 2006, 44(1),
95-98.
DOI:
10.1002/mrc.1723
- S. Pedersoli, M. G.
Constantino e G. V. J. da Silva, “1H and
13C
NMR Spectral
Data
for a Tricyclic Derivative of a Diels-Alder Adduct”, Magn.
Reson. Chem.
2006, 44(1), 83-86.
DOI:
10.1002/mrc.1714
- M. G. Constantino, K. T.
Oliveira,
E. C. Polo, G. V. J. da Silva e T. J. Brocksom, “Core Structure of
Eremophilanes and Bakkanes through Niobium Catalyzed Diels-Alder Reaction:
Synthesis of (±)-Bakkenolide A”, J. Org. Chem. 2006, 71,
9880-9883.
DOI:
10.1021/jo061722x
- M. G. Constantino, G.
V. J. da Silva, V. C. G.
Heleno,
I. A. Borin e I. P. de A.
Campos,
“Simulação de Desdobramentos
Complexos
de
Espectros
de RMN de 1H”,
Química
Nova
2006, 29(1),
160-167.
http://quimicanova.sbq.org.br/qn/qnol/2006/vol29n1/28-NT05046.pdf
- G. F. Caramori, K. T.
Oliveira,
S. E. Galembeck, P. Bultinck e M. G. Constantino, “Aromaticity and
Homoaromaticity in Methano[10]annulenes”, J. Org.
Chem.
2007, 72(1), 76-85.
DOI:
10.1021/jo061702v
- V. L.
Júnior,
M. G. Constantino, G. V. J. da Silva, Álvaro
Cunha
Neto e
Cláudio F. Tormena, “NMR and Theoretical Investigation of the Keto-enol
Tautomerism in Cyclohexane-1,3-diones”, J. Mol. Struc. 2007,
828(1-3), 54-58.
DOI:
10.1016/j.molstruc.2006.05.036
- M. G. Constantino, V.
L.
Júnior,
P. R. Invernize, L. C. da Silva
Filho e
G. V. J. da Silva, “Opening of Epoxide Rings Catalyzed by Niobium
Pentachloride”, Synth. Commun. 2007, 37(20), 3529-3539.
UR
-
http://www.informaworld.com/10.1080/00397910701555790
- V. J.
Júnior,
K. T.
Oliveira,
Rodrigo
Costa
e Silva, M. G. Constantino e G. V. J. da Silva, “Reatividade
em
Reações
de Diels-Alder: Uma
Prática
Computacional”,
Química
Nova
2007, 30(3),
727-730.
http://quimicanova.sbq.org.br/qn/qnol/2007/vol30n3/37-ED06142.pdf
- M. G. Constantino, V. Aragão
e G.
V. J. da Silva, “An
Approach
to the Synthesis of Furanoheliangolides
Through Diels-Alder Reactions”,
Tetrahedron Letters 2008, 49, 1393-1395.
DOI:
10.1016/j.tetlet.2007.12.079
- V. L.
Júnior,
G. V. J. da Silva, M. G. Constantino, R. B. dos
Santos,
E. V. R. de Castro e R. C. Silva, “Stereochemistry of Ccyclopentane Derivatives
from 2,3JCH Dependence on Dihedral Angle (θ
H-C-C-X)”, Magn. Reson. Chem. 2008, 46(3), 268-273.
DOI:
10.1002/mrc.2182
-
D. C.
Sass, V. C. G. Heleno,
J. L. C. Lopes e M. G. Constantino,
“One-step
Biomimetic Conversion of a
Furanoheliangolide into an Eremantholide
Using Stryker's
Reagent”,
Tetrahedron Letters 2008, 49,
3877-3880.
-
D. C.
Sass, K. T.
Oliveira
e M. G. Constantino,
“Synthesis
of Homoallylic Oxygenated
alfa-methylene-gamma-butyrolactones: a Model for
Preparing Biologically
Active Natural
Lactones”,
Tetrahedron Letters 2008,
49, 5770-5772.
-
L. C. da Silva
Filho, V. L.
Júnior,
M. G. Constantino e
G. V. J. da Silva,
“Fast
and Efficient Synthesis of Pyrano[3,2- c ]quinolines
Catalyzed by Niobium(V) Chloride”,
Synthesis”,
Journal of Synthetic Organic
Chemistry 2008, 2527-2536.
-
E. C.
Polo,
L. C. da Silva
Filho,
SILVA, G. V. J. da Silva e
M. G. Constantino,
“Síntese
de 1-Indanonas Através da Reação de Acilação de Friedel-Crafts Intramolecular
Utilizando NbCl5 Como Ácido de Lewis”, Química Nova 2008, 31,
763-766.
- T. J. Brocksom,
U. Brocksom e M. G. Constantino,
“A
Síntese
dos Sesquiterpenos Baquenolidas”,
Química
Nova
2008,
31, 937-941.
- D. Frederico, M. G. Constantino e P. M. Donate,
“Total Synthesis of
(3S, 5R, 3'S, 5'R)-Capsorubin”,
Journal of the Brazilian Chemical Society 2009,
20, 888-894.
-
D. C.
Sass, V. C. G. Heleno,
G. O. Morais, J. L. C. Lopes, N. P. Lopes e M. G. Constantino,
“Selectivity in
Reduction of
Natural
Furanoheliangolides with Stryker's
Reagent”,
Organic & Biomolecular Chemistry 2011,
9, 6148.
-
D. C.
Sass, E. C. De Lucca, J. S. Barbosa, K. T.
Oliveira
e M. G. Constantino, “Tandem
Reduction + Cyclization of
ortho-Substituted Cinnamic
Esters”,
Tetrahedron Letters
2011, 52, 5371-5374.
-
D. C.
Sass, V. C. G. Heleno, A. C. F. Soares, J. L. C. Lopes e M. G. Constantino,
“Detailed
1H and 13C NMR structural assignment and relative
stereochemistry determination for three new and one known semi-synthetic
sesquiterpene lactones”,
Journal of
Molecular Structure 2012, 1008, 24-28.
- A. F. Nascimento, M. G. Constantino e P. M. Donate,
“Total Synthesis of
Aripuanin, a Megastigmane from Ficus aripuanensis”,
Orbital: The Electronic
Journal of Chemistry 2012,
4, 253-262.
-
S. M. M. Rodrigues,
V. Nardini,
M. G. Constantino
e G. V. J. da Silva,
“Cerium
Metal-mediated Reformatsky-type
Reaction with
Ethyl
Bromosuccinate for the
Synthesis of
Novel
Paraconic
Acid
Analogs”,
Tetrahedron Letters 2012, 53, 6136-6137.
-
D. C.
Sass, V. C. G. Heleno, S. Cavalcante, J. N. Silva, A. C. F. Soares e M. G. Constantino,
“Solvent Effect in
Reactions Using Stryker s Reagent”,
Journal of Organic Chemistry 2012,
77, 9374-9378.
-
V. Nardini,
S. M. M. Rodrigues,
M. G. Constantino
e G. V. J. da Silva,
“Side-chain
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